I hope you aren't here just to score some new anime titles to watch. Becayse that'd suck if you missed out on the cool community that seems to be building here.
From what I read, you haven't seen any of the Tenchi Muyo series. Tenchi roooocks.
I have never personally seen it, but FruitsBasket is supposed to be good for romance too.
If you like mechs, check out G Gundam.
For a combination of love and mech / bounty hunter stuff, watch Outlaw Star.
Finally, the one I tell everyone to watch just because it's so good: Mushishi.